As such, the specific mechanisms of iascc remain unknown. Filmrupture stress ruptures local passive films and create an activepassive cell. Environmental cracking or environmentally assisted cracking eac is the cracking of a material wherein an interaction with its environment is a causative factor in conjunction with tensile stress authors note. Irradiationassisted stress corrosion cracking is a key materials degradation issue in todays nuclear power reactor fleet and affects critical structural components within the reactor core.
Under these suitable conditions, brittle and catastrophic failure occurs at levels much lower than the materials ultimate tensile strength. In recent years, failures of reactor internal components have been observed after the components have reached neutron fluence levels 5 x 10 20 ncm2 e 1 mev. Field experience as well as laboratory test results are considered to illustrate how iascc already impacts plant operation. However, this discussion will focus on the normal usage of the term as defined below. Irradiation assisted stress corrosion cracking iascc. The effects of increased exposure to irradiation, stress, andor coolant can substantially increase susceptibility to stresscorrosion cracking of austenitic steels in hightemperature water environments. There are several different models to explain environmental cracking, such as. Observed at several plants scc is a potentially significantobserved at several.
Download citation irradiation assisted stress corrosion cracking iascc irradiation assisted stress corrosion cracking iascc is a potential failure mode suffered by the corecomponents of. Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components of nonsensitized austenitic stainless steel. Irradiationassisted stress corrosion cracking iascc occurs above a critical neutron fluence in lightwater reactor lwr water environments at 288 c, but very little information exists to indicate susceptibility as temperatures are reduced. Study of the effect of swelling on irradiation assisted.
Irradiationassisted stress corrosion cracking behavior of austenitic stainless steels applicable to lwr core internals. Shack abstract this report summarizes work performed at argonne national laboratory on irradiationassisted stress. Stressrelief cracking is also known as postweld heat treatment cracking. Environmental cracking refers to a corrosion cracking caused by a combination of conditions that can specifically result in one of the following form of corrosion damage. Stress corrosion cracking scc is an important degradation mechanism for. Effects of irradiation on intergranular stress corrosion. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. It usually occurs at stress raisers, is intergranular in nature, and is generally observed in the coarsegrained region of the weld heataffected zone. Because iascc accelerates the deterioration of various reactor components, it is imperative that it be understood and modeled to maintain reactor safety.
Stress assisted corrosion is a type of corrosion that can occur in metals due to elevated static tensile stress levels. Irradiationassisted stress corrosion cracking iascc refers to the processes by which irradiation enhances the inherent susceptibility of alloys to stress corrosion cracking scc. Comparative stress corrosion cracking and general corrosion resistance of annealed and hardened 440c stainless steelnew techniques in stress corrosion testing m. Phenomenon of irradiation assisted stress corrosion cracking for. Internal components of nuclear reactor pressure vessels are fabricated primarily from austenitic stainless steels because of their relatively high strength, ductility, and fracture toughness. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack growth rates associated with stress corrosion to. Amine cracking typically occurs on the surface and the cracks are usually radially. Occasionally, both types of cracking are observed in a failure. Irradiation assisted stress corrosion cracking ias. These mechanisms can act individually or act in combination to accelerate the aging processes. Laboratory testing of metals for resistance to sulphide stress cracking and stress corrosion cracking in h 2 s environment 27 tm01982004 slow strain rate test method for screening corrosionresistant alloys cras for stress corrosion cracking in sour oilfield service 3 astm test methods complementary to iso standards 28. Irradiation has a profound effect on the stress corrosion cracking propensity of austenitic alloys in hightemperature water.
Broadly speaking, iascc can result from effects on the materials, andor environment by gam mas, neutrons, electrons or ions. Stress corrosion cracking of highstrength steels abstract. Irradiationassisted stress corrosion cracking as a factor. The mechanism by which dislocation channeling induces irradiation assisted stress corrosion cracking was determined using fecr15ni austenitic stainless steel irradiated with protons to a dose of 5 dpa and strained at high temperature in both argon and simulated boiling water reactor normal water chemistry environments. Effects of fluoride and other halogen ions on the external. Following irradiation, the material was very susceptible to iascc. This paper deals with fracture of neutron irradiated austenitic tistabilized stainless steel 08ch18n10t. The mechanism by which dislocation channeling induces irradiation assisted stress corrosion cracking was determined using fecr15ni austenitic stainless. This report summarizes work performed at argonne national laboratory on irradiationassisted stress corrosion cracking iascc of austenitic stainless steels that were irradiated in the halden reactor in simulation of irradiationinduced degradation of boiling water reactor bwr core internal components. I began to apply this to the irradiation assisted stress corrosion cracking problem which led to a longterm effort at solving the mechanism of this mode of degradation. Structural alloys for generationiv nuclear reactors need to endure a high neutron dose, high temperature, and corrosive coolant. Study on irradiation assisted stress corrosion cracking of nuclear.
Iascc is apparently a timedependent phenomenon, which does not manifest itself until a minimum residence time or threshold fast neutron. Irradiationassisted stress corrosion cracking behavior of austenitic stainless steels applicable to lwr core internals by h. It is referred to as assisted because irradiation enhances, or accelerates the igscc process over the unirradiated state. Slow strain rate and crack growth rate tests were performed in the water. A major problem is stress corrosion cracking, which combines chemical attack in the form of corrosion with stress from mechanical loads. Irradiationassisted stresscorrosion cracking iascc is a complicated phenomenon that poses a difficult problem for designers and operators of nuclear plants. Irradiation assisted stress corrosion cracking iascc refers to intergranular stress corrosion cracking that is accelerated under the action of irradiation in light water reactor core components. Irradiationassisted stress corrosion cracking of model.
Irradiation in high temperature water generally accelerates both general corrosion and stress corrosion cracking. Micromechanistic origin of irradiationassisted stress. Irradiationassisted stress corrosion cracking of austenitic. Irradiation assisted stress corrosion cracking request pdf. Irradiationassisted stress corrosion cracking osti.
Irradiation assisted stress corrosion cracking iascc is a term which has been used in recent years to describe intergranular cracking showing little or no ductility which can occur in heavily irradiated struc tural components of nuclear reactor cores. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. The elevated susceptibility to scc in irradiated materials, commonly referred to as irradiationassisted stress corrosion cracking iascc, is a complex phenomenon that involves simultaneous actions of irradiation, stress, and corrosion. Irradiationassisted stress corrosion cracking behavior of. Detection of stress corrosion cracking by sonicir technique. The surfacemobility scc mechanism accounts for the observation made in the present work, and the activation energy predicted in iodide solutions is similar to that found in the literature. Irradiation assisted stress corrosion cracking iascc is an intergranular cracking effect which can occur in heavily irradiated internal structural components of nuclear reactor cores. Phenomenon of irradiation assisted stress corrosion. For example, flow accelerated corrosion fac, corrosion fatigue cf, and irradiationassisted.
Irradiationinduced stress corrosion cracking of austenitic stainless steels. Study on irradiation assisted stress corrosion cracking of nuclear grade 304 stainless steel. Irradiation assisted stress corrosion cracking ias cc refers to the acceleration of the scc process by irradiation. A mechanistic basis for irradiation assisted stress. Irradiationassisted,stress corrosion cracking iascc of austenitic stainless steel ss is known to occur in water environments at temperatures near 288c, but very little information exists to indicate susceptibility as temperatures are reduced. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Unfortunately, the costs and dangers of gathering data on radiation effects.
Abstract irradiationassisted stress corrosion cracking iascc refers to the processes by which irradiation enhances the inherent susceptibility of alloys to stress corrosion cracking scc. Irradiationassisted stress corrosion cracking iascc is a form of intergranular stress corrosion cracking igscc that has occurred infrequently during the last two decades in incore components. As light water reactors age and materials accumulate increasing. Corrosion causes a material to age in a particular manner and speed, and stress causes it to fracture after a certain period of time, says bilge yildiz, associate professor of nuclear science and. Potential lowtemperature behavior is assessed based on the temperature dependencies of intergranular ig scc in the absence of irradiation, radiation. Micromechanistic origin of irradiationassisted stress corrosion. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stressrelief cracking occurs only in metals that can precipitationharden during such elevatedtemperature exposure. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. Irradiationassisted stress corrosion cracking and impact. Liquid metal crackinglmc, usually a physicochemical process. In materials science, environmental stress fracture or environment assisted fracture is the generic name given to premature failure under the influence of tensile stresses and harmful environments of materials such as metals and alloys, composites, plastics and ceramics metals and alloys exhibit phenomena such as stress corrosion cracking, hydrogen embrittlement, liquid metal embrittlement. Role of irradiated microstructure and microchemistry in. In the solution annealed, unirradiated condition, the stainless steel was resistant to stress corrosion cracking.
This article begins with an introduction to the iascc problem experienced in light water reactors, followed by a summary of existing plant and laboratory data that reveal its dependence on irradiation. Auger analysis and corrosion testing indicated that the irradiated material was no longer free of grain boundary segregation. The paper aims to give a present status of knowledge on irradiationassisted stress corrosion cracking iascc from the point of view of nuclear power plant life extension. Irradiationassisted stress corrosion cracking iascc has been well documented both in the laboratory and in service over the past two decades. While irradiation is believed to accelerate corrosion of most components in the core, the components initially observed to crack prematurely were primarily small components bolts, springs, etc. Amine cracking is a form of stress corrosion cracking, which is related to alkaline and carbonate stress corrosion cracking. There is no single mechanism that can describe environmental cracking. Danford marshall space flight center, marshall space flight center, alabama national aeronautics and space administration. Irradiationassisted stress corrosion cracking, corrosion.
Micromechanistic origin of irradiationassisted stress corrosion cracking. One common misconception is that scc is the result of stress concentration at corrosion. Mechanism of dislocation channelinduced irradiation. Assessment of initial test conditions for experiments to. Irradiation assisted corrosion and stress corrosion. However, the detection and sizing of scc is extremely difficult by the conventional nondestructive testing techniques due to the crack closure. Specifically, it is a stress attack directed at locations where applied or residual stresses are imparted to the metal. Such cracks have been seen in a number of internal components in boiling water reactors bwrs. Irradiationassisted stress corrosion cracking of model austenitic stainless steel alloys nuregcr6687. Amine cracking is often intertwined with wet hydrogen sulfide h 2 s and carbonate cracking, as amines, carbonates and wet sulfides often exist together in amine treating systems.
The general pattern of the observed failures indicates that as nuclear plants age and fluence increases, various apparently nonsensitized austenitic. Fracture of irradiated austenitic stainless steel with. Introduction irradiation assisted stress corrosion cracking ias cc refers to the acceleration of the scc process by irradiation. At the same time, i used the opportunity to question whether heavy self ions could be used to reach high damage levels typical of lwr endoflife or fast reactors. Austenitic stainless steels, particularly the oxidedispersionstrengthened ods austenitic steels, are promising candidate materials, but they suffer several limits such as irradiation damage and stress corrosion cracking scc. Effects of irradiation on intergranular stress corrosion cracking. Stresses that cause environmental cracking arise from residual cold work, welding, grinding, thermal. The drip procedure from the standard test method for evaluating the influence of thermal insulation on external stress corrosion cracking tendency of austenitic stainless steel astm c 69295a was used to research the effect of halogens and inhibitors on the external stress corrosion cracking escc of type 304 stainless steel as it applies to nuclear regulatory commission. This behavior indicates that percent intergranular stress corrosion cracking determined at. Although fatigue is a degradation mechanism that is second in importance to radiation. The factors which influence degradation of these parts are.
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